The Electrical characterization of sodium cadmium borate glasses doped with TiO2

Keywords: Oxide glasses, Optical materials, Electrical conductivity, TiO2, borate glasses, electrical properties

Abstract

A glass series sodium cadmium borate glasses doped with titanium has been formed using melt quench technique within the composition 20Na2O-(20-x)CdO- 60B2O3-xTiO2 (0 ≤ x ≤ 5 mol%). The composition was prepared to study the effect of dopant (TiO2) on physical, optical and electrical properties of the glass series under study. The results of physical parameter i.e. density and molar volume show some structural changes at higher concentration of TiO2 doping. Some theoretical optical parameter parameters (n, Rm, αm and  ) were calculated and displayed in Table 2 & 3. The dc conductivity of the glasses is found temperature dependent. The conductivity value ranges in between 2.45x10-6 – 3.47x10-6 Scm-1 at 523 K temperature indicates the insulating behavior of these glasses.

Downloads

Download data is not yet available.

Author Biographies

Sonam Raheja, Apeejay Stya University

School of Engineering and Technology

Department of Physics

Assistant Professor

Ravinder Singh, School of Engineering and Technology, Apeejay Stya University

Department of Physics

Moin Uddin, Apeejay Stya University

School of Engineering and Technology

Distinguish Professor

References

Abouhaswa, A. S., Rammah, Y. S., Ibrahim, S. E., & El-Hamalawy,

A. A. (2018). Structural, optical, and electrical characterization of

borate glasses doped with SnO2. Journal of Non-Crystalline Solids,

, 59–65.

Alajerami, Y. S. M., Hashim, S., Wan Hassan, W. M. S., & Ramli, A.

T. (2012). The effect of titanium oxide on the optical properties of

lithium potassium borate glass. Journal of Molecular Structure, 1026,

–167.

Gomaa, H. M., Elkatlawy, S. M., Yahia, I. S., Saudi, H. A., & Abdel-

Ghany, A. M. (2021). Influence of the gradual increase of TiO2-

impurities on the structural and optical properties of some calcium

sodium borate glasses. Optik, 244, 167543.

Sadeq, M. S., Morshidy, H. Y., “Effect of mixed rare-earth

ions on the structural and optical properties of some borate glasses”,

, Ceramics International.

Rojas, S. S., De Souza, J. E., Yukimitu, K., & Hernandes, A. C.

(2014). Structural, thermal and optical properties of CaBO and

CaLiBO glasses doped with Eu3+. Journal of Non-Crystalline Solids,

-399, 57–

Nagamani, B., & Srinivasu, C. (2019). Physical parameters and

structural analysis of titanium doped binary boro silicate glasses by

spectroscopic techniques. Materials Today: Proceedings.

Marzouk, M. A., ElBatal, F. H., & ElBatal, H. A. (2016). Effect of

TiO2 on the optical, structural and crystallization behavior of barium

borate glasses. Optical Materials, 57, 14–22.

Anjaiah, J., Laxmikanth, C., Kistaiah, P., & Veeraiah, N.

(2014). Dosimetric and kinetic parameters of lithium cadmium borate

glasses doped with rare earth ions. Journal of Radiation Research and

Applied Sciences, 7(4), 519–525.

Umar, S. A.; Halimah, M. K.; Chan, K. T.; Latif, A. A.

Polarizability, Optical Basicity and Electric Susceptibility of

Er3+ Doped Silicate Borotellurite Glasses. J. Non-Cryst.

Solids 2017, 471, 101–109.

A, D. J. Electronic Polarisability and Related Properties of the

Oxide Ion. Phys. Chem. Glas. 1989, 30 (1), 1–4.

Duffy, J. A. (1993). A review of optical basicity and its applications

to oxidic systems. Geochimica et Cosmochimica Acta, 57(16), 3961–

V. Dimitrov, T. Komatsu, Correlation among

electronegativity, cation polarizability, optical basicity and

single bond strength of simple oxides. Journal of Solid-State

Chemistry 196 (2012) 574–578.

Shelby, J.E., Introduction to Glass Science & Technology,

nd edition, The Royal Society of Chemistry, 2005.

Elkhoshkhany, N.; El-Mallawany, R.; Syala, E. Mechanical

and Thermal Properties of TeO2–Bi2O3–V2O5–Na2O–

TiO2 Glass System. Ceram. Int. 2016, 42 (16), 19218–

Werner, A. J. Colour Generation and Control in Glass, by C.

R. Bamford. Elsevier Scientific Publishing Co., Amsterdam

and New York, 1977. 224 Pp., Color Res.Appl. 1978, 3 (3),

–156.

Sanghi, S.; Rani, S.; Agarwal, A.; Bhatnagar, V. Influence of

Nb2O5 on the Structure, Optical and Electrical Properties of

Alkaline Borate Glasses. Mater. Chem. Phys. 2010, 120 (2),

–386.

Published
2021-12-15
How to Cite
Raheja, S., Singh, R., & Uddin, M. (2021). The Electrical characterization of sodium cadmium borate glasses doped with TiO2 . PREPARE@u® | IEI Conferences. https://doi.org/10.36375/prepare_u.iei.a205
Section
- 36.IEC | Metallurgical & Materials Engineering